Qian Zhang (张谦) (Visiting Scholar)

Qian Zhang

Assistant professor
Hubei University of Technology
Wuhan 430068, P. R. China

Date and place of birth: 29 May 1986, Xinyang, Henan, China
Speciality: Organic Synthetic Methodology, Organometallic Chemistry, Organoiodine Chemistry.

Education (Academic Background):
University studies:
09/2003 – 07/2007 B.S. Chemistry, Zhengzhou University, China.
09/2007 – 07/2010 M.S. Organic Chemistry, Laboratory of Biological chemistry, Chemical Department, Zhengzhou University. (Advisor: Prof. Xincheng Liao)
09/2010 – 07/2014 Ph.D. Organic Chemistry, ZhengZhou University, China (Advisor: Academician: Yangjie Wu)
Career:
09/2014 – now Assistant professor in school of materials and chemical engineering, Hubei University of Technology, Wuhan, China.
12/2018 – 07/2019 Visiting Scholar, Professor Yorimitsu. Kyoto University, Japan
Funding
Novel transition-metal-catalyzed halogenation reactions, Open Project Program of Hubei Key Laboratory of Drug Synthesis and Optimization (2016–2017)
Nucleophilic oxidative halogenation of inert sp3 C-H bond by using metal halides, National Natural Science Foundation of China (No. 21702054) (2018–2020)
Publications:
1. Zhong Zhou, Huihui Ji, Qing Li, Qian Zhang*, Dong Li, Direct C–H aminocarbonylation of N-heteroarenes with isocyanides under transition metal-free conditions, Org. Biomol. Chem., 2021, 19, 2917.
2. Zhong Zhou, Yunli Wu, Peng Yang, Shijun Deng, Qian Zhang*, Dong Li*, Silver-Catalyzed Cross Dehydrogenative Coupling between Heteroarenes and Cyclic Ethers under Mild Conditions, ChemistrySelect 2021, 6, 2770.
3. Qian Zhang, Kenshiro Hitoshio, Hayate Saito, Jun Shimokawa*, Hideki Yorimitsu*, Copper-Catalyzed Electrophilic Amination of Alkoxyarylsilanes, Eur. J. Org. Chem. 2020, 4018.
4. Ruinan Zhao, Zhong Zhou, Jixiang Liu, Xia Wang, Qian Zhang*, Dong Li*, Silver-Catalyzed para-Selective Amination and Aminative Dearomatization of Phenols with Azodicarboxylates in Water, Org. Lett., 2020, 22, 8144.
5. Xia Wang, Bo Hu, Peng Yang, Qian Zhang*, Dong Li*, Synthesis of vinyl sulfones through sulfonylation of styrenes with sulfonyl chlorides under metal-free conditions, Tetrahedron, 2020, 76, 131082.
6. Xia Wang, Hao Liu, Dehu Xiang, Qian Zhang*, Dong Li*, Hypervalent Iodine Reagent-Mediated Selective Vinyl C-H Amidation of 4-Alkoxystyrenes with Diarylsulfonimides for Preparation of Enamides, ChemistrySelect, 2020, 5, 5970.
7. Qian Zhang, Juanjuan Li, Jiale Li, Songdong Yuan, Dong Li, An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides, Tetrahedron Letters, 2020, 61, 152399.
8. Dehu Xiang, Huan Li, Ling Zhang, Yunhua Zhang, Qian Zhang*, Dong Li*, Divergent Reactions between Alkynes and Dibenzenesulfonimide: Selective Synthesis of Ynamides and Enamides under Metal-Free Conditions, Asian J. Org. Chem. 2019, 8, 537.
9. Juanjuan Li, Jiale Li, Songdong Yuan, Qian Zhang,*, Dong Li*, Cobalt-Catalyzed Oxyalkylation of Styrenes via α-C(Sp3)-H Bond Activation of Ethers Without Organic Peroxides, Asian J. Org. Chem., 2019, 8, 1.
10. Qiang Yue, Zhen Xiao, Zhengkun Kuang, Zhengding Su, Qian Zhang,*, Dong Li,* Chelation-promoted efficient C–H/N–H cross dehydrogenative coupling between picolinamides and simple ethers under copper catalysis, Adv. Synth. Catal., 2018, 360, 1193.
11. Qiang Yue, Zhen Xiao, Ziyao Ran, Songdong Yuan, Qian Zhang*, Dong Li*, Copper-catalyzed α-C–H amidation of simple ethers through C(sp3)–H/N–H cross dehydrogenative coupling, Org. Chem. Front., 2018, 5, 967.
12. Yaocheng Yang, Yanting Yu, Yang Wang, Qian Zhang*, Dong Li*, Metal-free remote oxidative benzylic C–H amination of 4-methylanilides with N-fluorobenzenesulfonimide, Tetrahedron 2018, 74 1085.
13. Dehu Xiang, Lan Xia, Yunhua Zhang, Qian Zhang*, Dong Li *, Remote oxidative C−H amidation of anilides with dibenzenesulfonimides under metal-free conditions, Synlett., 2018, 29, 1400.
14. Yang Wang, Ying Wang, Qian Zhang*, Dong Li*, Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions, Org. Chem. Front., 2017, 4, 514.
15. Yang Wang, Ying Wang, Zhenyu Guo, Qian Zhang*, Dong Li*, Metal-free oxidative C–H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide Asian J. Org. Chem., 2016, 5, 1438.
16. Qian Zhang, Yang Wang, Tingting Yang, Li Li, Dong Li*, Palladium catalyzed ortho-C–H-acylation of 2-arylpyridines using phenylacetylenes and styrene epoxide, Tetrahedron Lett., 2016, 57, 90.
17. Ying Wang, Yang Wang, Kai Jiang, Qian Zhang*, Dong Li*, Transition-metal-free oxidative C5 C–H-halogenation of 8-aminoquinoline amides using sodium halides, Org. Biomol. Chem., 2016, 14, 10180.
18. Guodong Zhang, Suyan Sun, Fan Yang,* Qian Zhang, Jianxun Kang, Yusheng Wu,* and Yangjie Wua,* Arylmethyl chlorides: new bifunctional reagents for palladium-catalyzed ortho-chlorination and acylation of 2-arylpyridines, Adv. Synth. Catal., 2015, 357, 443.
19. Qian Zhang, Ying Wang, Tingting Yang, Li Li, Dong Li*, Palladium catalyzed ortho-C–H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates, Tetrahedron Lett., 2015, 56, 6136.
20. Qian Zhang, Fan Yang*, Yangjie Wu*, DDQ: the chlorinating reagent and oxidant for the ligand-directed ortho-chlorination of 2-arylpyridines, Org. Chem. Front., 2014, 1, 694.
21. Qian Zhang, Chao Li, Fan Yang*, Jingya Li, Yangjie Wu*, Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles, Tetrahedron 2013, 69, 320.
22. Qian Zhang, Fan Yang*, Yangjie Wu*, Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles and 2-arylbenzothiazoles using arylmethyl alcohols as the acyl source, Tetrahedron 2013, 69, 4908.
23. Qian Zhang, Fan Yang*, Yangjie Wu*, Palladium-catalyzed ortho-acylation of 2-aryl pyridine derivatives using arylmethyl amines as new acyl sources, Chem. Commun., 2013, 49, 6837.
24. Peng Yang, Xia Wang, Liang Wang, Jiahua He, Qian Zhang, Dong Li*, Oxidative cross-dehydrogenative coupling between iodoarenes and acylanilides for C–N bond formation under metal-free conditions, Org. Chem. Front., 2021, 8, 2556.
25. Xia Wang, Peng Yang, Bo Hu, Qian Zhang, Dong Li*, Hypervalent Iodine Reagent-Promoted Hofmann-Type Rearrangement/Carboxylation of Primary Amides, J. Org. Chem., 2021, 86, 28